Formulation based predictive cure kinetics modelling of epoxy resins

نویسندگان

چکیده

Matrix formulation for aero-grade high-performance carbon fibre reinforced thermoset composites is a challenging task relying on extensive knowledge of chemistry, legacy information and trial-and-error iterations to identify suitable pre-polymer resin/curative combination. This work proposes the development application cure kinetics methodology tailor preliminary matrix formulations focusing constituents reactivity. The ternary system containing either one epoxy two amine curatives or pre-polymers curative approximated as linear combination its elementary binary systems corresponding curative. method has been evaluated wide range epoxy/amine shown be valid with reaction rate error lower than 0.003 min−1. this predictive allows design tailored reactivity time without experimentation.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and Cure Kinetics of Liquefied Wood/Phenol/ Formaldehyde Resins

Wood liquefaction was conducted at a 2/1 phenol/wood ratio in two different reactors: (1) an atmospheric three-necked flask reactor and (2) a sealed Parr reactor. The liquefied wood mixture (liquefied wood, unreacted phenol, and wood residue) was further condensed with formaldehyde under acidic conditions to synthesize two novolac-type liquefied wood/phenol/formaldehyde (LWPF) resins: LWPF1 (th...

متن کامل

Cure Kinetics and Rheology Characterization of Soy-based Epoxy Resin System

A novel soy-based epoxy resin system was synthesized by the process of transesterification and epoxidation of regular soy bean oil, which has the potential to be widely usable in various composite manufacturing processes. Cure kinetics and rheology are two chemical properties commonly required in process modeling. In this work, the cure kinetics and rheology of the soy-based resin system were m...

متن کامل

Epoxy Resins in Electron Microscopy

A method of embedding biological specimens in araldite 502 (Ciba) has been developed for materials available in the United States. Araldite-embedded tissues are suitable for electron microscopy, but the cutting qualities of the resin necessitates more than routine attention during microtomy. The rather high viscosity of araldite 502 also seems to be an unnecessary handicap. The less viscous epo...

متن کامل

Synthesis and Characterizations of Melamine-Based Epoxy Resins

A new, easy and cost-effective synthetic procedure for the preparation of thermosetting melamine-based epoxy resins is reported. By this innovative synthetic method, different kinds of resins can be obtained just by mixing the reagents in the presence of a catalyst without solvent and with mild curing conditions. Two types of resins were synthesized using melamine and a glycidyl derivative (res...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Polymer

سال: 2021

ISSN: ['1873-2291', '0032-3861']

DOI: https://doi.org/10.1016/j.polymer.2021.124304